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The Huge Purple Glowshroom is a structure added by Natura that can be found in the Nether. It has no Overworld counterpart, but will still drop Purple Glowshrooms upon destruction like the huge Overworld mushrooms and the huge Nether varieties.
The tops of the Huge Purple Glowshroom can be stood on, but the sides of the same blocks can be walked through, which will induce Nausea for 5 seconds.