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The Huge Purple Glowshroom is a mushroom structure added by Natura that can be found in the Nether. It does not spawn in the Overworld, and doesn't have a counterpart that does. When the mushroom is mined, it will drop Purple Glowshrooms upon destruction like the huge Overworld mushrooms.
The tops of the Huge Purple Glowshroom can be stood on, but the sides of the same blocks can be walked through, which will induce Nausea for 5 seconds.